Chemistry, asked by Ashujatav3679, 1 year ago

the solution of cuso4 in which copper rod is immersed is diluted to 10 times

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Answered by brainusers
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If solution is diluted to 10 times , molar conc. CU2+" role="presentation" style="display: inline; font-style: normal; font-weight: normal; line-height: normal; font-size: 13px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">CU2+CU2+is reduced to obe tenth of its original value

Nernst equation for CU2++2e−1→Cu" role="presentation" style="display: inline; font-style: normal; font-weight: normal; line-height: normal; font-size: 13px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">CU2++2e−1→CuCU2++2e−1→Cu

is

E=E++0.0592" role="presentation" style="display: inline; font-style: normal; font-weight: normal; line-height: normal; font-size: 13px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">E=E++0.0592E=E++0.0592log⁡[cu2+]" role="presentation" style="display: inline; font-style: normal; font-weight: normal; line-height: normal; font-size: 13px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">log[cu2+]log⁡[cu2+]

By decreasing the conc. of Cu2+" role="presentation" style="display: inline; font-style: normal; font-weight: normal; line-height: normal; font-size: 13px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">Cu2+Cu2+ by 110,E" role="presentation" style="display: inline; font-style: normal; font-weight: normal; line-height: normal; font-size: 13px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">110,E110,E

will decrease by 0.0592" role="presentation" style="display: inline; font-style: normal; font-weight: normal; line-height: normal; font-size: 13px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">0.05920.0592

(i.e) approx by 0.03V" role="presentation" style="display: inline; font-style: normal; font-weight: normal; line-height: normal; font-size: 13px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">0.03V


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