The standard emf of a cell, involving one electron change is
found to be 0.591 V at 25°C. The equilibrium constant of the
reaction is (F = 96500 C mol⁻¹)
(a) 1.0 × 10¹ (b) 1.0 × 10⁵
(c) 1.0 × 10¹⁰ (d) 1.0 ×10³⁰
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The equilibrium constant of the reaction is 1×10¹⁰
- = 0.591 V
- T = 25°C = 25 + 273 K = 298 K
- F = 96500 C mol⁻¹
- n = 1
- R = 8.314 J/K
- using formula : = (2.303 RT/nF) × log
log = nF/ 2.303 RT
= (1 × 96500 × 0.591)/ (2.303 × 8.314 × 298)
log = 10
=
- So the correct answer is option (c) 1.0 × 10¹⁰
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