The surface phenomena is
(1) evaporation. (2) sublimation.
(3) condensation. (4) cooling.
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Boiling is a bulk phenomenon because all molecules get energy on heating.
Evaporation is a surface phenomenon as the molecules of the surface gets sufficient energy to overcome the force of attraction which will help in converting to the vapor phase.
Dilution is also a bulk phenomenon as the volume of solution increases in the whole solution.
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