The synthesis of 3-octyne is achieved by adding a bromoalkane into a mixture of sodium amide and an alkyne. The bromoalkane and alkyne respectively are (a) BrCH₂CH₂CH₂CH₂CH₃ and (b) BrCH₂CH₂CH₃ and (c) BrCH₂CH₂CH₂CH₂CH₃ and (d) BrCH₂CH₂CH₂CH₃ and
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