The value for the reverible isothermal evaporation of 90gm water at 100C' will be (DELTA H evap. OF WATER =40.8kJ/mol)and R=8.314 J perkelvin per mole
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Answer:
Given,
Water⟶vapour
Moles before evaporation
18
90
=5 0
The evaporation of 5 moles of water takes place reversibly and isothermally into vapours.
Thus, heat given at constant pressure:
ΔH=heatofevaporation×amountevaporated
=540×90
ΔH=48600cal
Also, ΔH=ΔU+Δn
(g)
RT
ΔU=48600−Δn
(g)
RT
=48600−5×2×373
=48600−3730
ΔU=44870cal
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