The value of gyromagnetic ratio g
is equal to 2.0023 for-
(A) Free electrons
(B) Free radicals
(C) Transition metal ions
(D) All species containing unpaired
electrons
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The value of gyromagnetic ratio g is equal to 2.0023 for (A) free electrons.
Explanation:
- In physics, the gyromagnetic ratio refers to the ratio of the magnetic momentum (magnetic dipole moment) in a spinning charged particle to its angular momentum.
- The gyromagnetic ratio (also called g- factor) denoted by "γ" is different for each nucleus of different atoms.
- A Soviet physicist Zavoiski in the year 1945, discovered the phenomenon of electron spin resonance which is used in ESR spectroscopy.
- For a free electron, the value of g is 2.0023. In many free radicals, the value of an odd electron is close to a free electron value.
- This splitting of spin is expressed by gβH.
where g is the g factor
β is the value of the Bohr magneton,
H is the magnetic field intensity.
- The value of the g-factor is equal to in the case of "spin only" (since the unpaired electrons possess less contribution towards the magnetic moment.)
Hence Option (A) free electrons is correct.
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