The value of unit weight of water is always taken as unity. Why?
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For solids or liquids, as mass decreases the volume also decreases by a proportional amount. 1000L water and 10mL water both have molar densities of 55.5 mol/L. So molar density variations are minimum and hence the variations in molar activity is minimum. So the activity coefficient is taken as unity.
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Explanation:
For solids or liquids, as mass decreases the volume also decreases by a proportional amount. 1000L water and 10mL water both have molar densities of 55.5 mol/L. So molar density variations are minimum and hence the variations in molar activity is minimum. So the activity coefficient is taken as unity.
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