the Vander Waal constant a and b for a gas are 0.21 and 0.017 in dm³ atm units . calculate the inversion temperature of the gas.
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Answer:
220k ..................
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Gases become cooler during Joule Thomson's expansion only if they are below a certain temperature known as inversion temperature (T
i
).
The inversion temperature is characteristic of each gas and is given by T
i
=
bR
2a
where R is gas constant
Given:
a=0.244 atm L
2
mol
−2
b=0.027 L mol
−1
R=0.0821 L atm K
−1
mol
−1
∴T
i
=
0.027×0.0821
2×0.244
=220 K
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