the vessel contains helium and methane in 4:1 molar ratio at 20 bar pressure due to leakage mixture of gases start effusion. composition of mixture effusing out
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Pressure=20bar
Molarratio=4:1(HeandCH 4 )
P He = 5
4 ×20=16bar
PCH4
= 5
1 ×20=4bar
r2r1= P2
P1 ×M1
M2
rCH4
r He
= P CH4
PHe×MHe
MCH4
=416 × 416 =8
Therefore, the ratio of moles of helium and methane coming out initially is 8:1.
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