The volue of
State of a. H-atom in
of normalization constant of ist excited
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Answer:
Explanation:
In the previous lecture we have solved the eigenvalue problem for the hydrogen atom,
Hˆψ(r, θ, ϕ) = Eψ(r, θ, ϕ) (1)
where the Hamiltonian is
Hˆ = −
h¯
2
2µ
∇2 + V (r)
with the reduced mass of the atom
µ = memp/(me + mp)
and the Coulomb potential V (r) = −e
2/r.
We have also seen that the Hamiltonian with a spherically symmetric potential energy function
commutes with the angular momentum operators Lˆ
z and Lˆ2
:
[Lˆ
z, Hˆ ] = 0, [Lˆ2
, Hˆ ] = 0
and of course also [Lˆ
z, Lˆ2
] = 0, and this implies that Hˆ , Lˆ
z and Lˆ2 have common eigen functions,
i.e. that we have also
Lˆ2ψ(r, θ, ϕ) = h¯
2
`(` + 1) ψ(r, θ,
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