The water sample (40 mL) requires 9.6 mL of 0.01 M EDTA solution
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M1V1=M2V2
50×M1=501×0.1
M1(HCO3−)=25×1031
mmoles of (HCO3−)=25×1031×50=5001
mmoles of Ca2+=10001
mmoles of CaCO3=10001
weight of CaCO3=10001×10−3×100=10−4g
Hardness = [weight of CaCO3 /weight of water] ×106=5010
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