third law of thermodynamic deals with
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The Third Law of Thermodynamics is concerned with the limiting behavior of systems as the temperature approaches absolute zero. Most thermodynamics calculations use only entropy differences, so the zero point of the entropy scale is often not important. However, we discuss the Third Law for purposes of completeness because it describes the condition of zero entropy.
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The Third law of thermodynamics is sometimes stated as follows, regarding the properties of closed systems in thermodynamic equilibrium:
The Entropy of a system approaches a constant value as its temperature approaches absolute zero.
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