ti2+ is coloured ion whereas ti4+ is colourless
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The ground state electronic configuration of Ti(22):[Ar]4s 2 3d 2
For Ti 2+ ion, the ground state electronic configuration is [Ar]3d 2
.
It contains two unpaired electrons. Thus d-d transition is possible.
For Ti 4+ ion, the ground state electronic configuration is [Ar]3d
0
.
All the electrons are paired. Hence, d-d transition is not possible and it is colourless.
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