to neutralize completely 20 ML of 0.1M phosphoric acid solution ,The volume of 1M KOH SOLUTION RQUIRED IS
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Explanation:
The neutralization reaction is H
3
PO
3
+2KOH→K
2
HPO
3
+2H
2
O.
Phosphorus acid is diprotic acid as it has two ionizable hydrogens.
Thus, 1 mole of phosphorous acid will neutralize 2 moles of KOH.
The number of moles of phosphorus acid present in 20 mL of 0.1 M aqueous solution is 0.1×20×
1000
1
=0.002 mol.
They will neutralize 2×0.002 mol =0.004 moles of KOH.
The molarity of KOH solution is 0.1 M.
The volume of KOH solution required will be
0.1
0.004
=0.04L=40 ml.
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