Chemistry, asked by Anonymous, 1 year ago

Two elements A and B form compounds having molecular formula AB2 and AB4 when dissolved in 20 gram of benzene, one gram of AB2 lowers the freezing point by2.3 Kelvin whereas 1.0 gram of AB4 lowers it by 1.3 Kelvin. calculate the atomic mass of A and B.

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Anonymous: plzz.. fast

Answers

Answered by Mocka
3
A+2B = 110.87
A+4B = 196.15
solving we get A = 42.64
B= 25.59
(cryscopic constant is considered 5.1 )

Mocka: ans is right??
Anonymous: bcoz I found problem in value of kf and u solve it
Mocka: welcome
Anonymous: but u don't solve it full
Anonymous: no problem I'll manage
Mocka: yeah
Mocka: won't you have the formula,?
Anonymous: no I have that's why I'm saying I'll manage
Mocka: ok
Mocka: t = k×(w × 1000)/(w'×m) : k is kf . w is mass of solute. w' is mass of solvent . m is molecular weight of solute. I think it will help you. ok bye.
Answered by DJstorm
1

Answer:

the atomic mass of a is 25.59 g/mol and b is 42.64 g/mol

Explanation:

As we know that,

MB=(kf×WB×1000)/(WA×deltaTf)

Now deltaTf =2.3, WB=1.0, WA=20,KF=5.1( given)

putting tye values in the equation.

MB=(5.1×1×1000)/(20×2.3)

=110.87 g/mol

Therefore Mab2=110.9

for AB4 compound

delta Tf=1.3,WB=1,Wa=20

MB=(5.1×1×1000)/(20×1.3)

=196g/mol

therefore MAB=196

Let x be the atomic masw of Aand y be the atomic mass of B

Then MAB2=x+2y=110.9______(1)

&MAB=x+4y=196________(2)

subtracting (2)from(1)

we get,

2y=196-110.9

y=85.1/2

y= 42.6

putting tye value of y in (1)

we get,

x=110.9 -2×42.6

x=25.59

Therefore, Atomic mass of A=25.59U and Atomic mass of B =42.6U.

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