Two gases h2 and o2 effuse from two different containers having same pressure and temperature. If the area of cross section of hole is 1:2 then the rate of effusion will be
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Let the rate of effusion of H2 be “r1” and of O2 be “r2”. Also, let the area of cross-section of hole for H2 be “A1” and for O2 be “A2”.
The ratio of A1 : A2 is given as = 1 : 2
The molecular mass of H2, M1 = 2 g/mol
The molecular mass of O2, M2 = 32 g/mol
We know that, when there is a small hole in the container with area of cross-section "A" , then
The rate of effusion is = J(impingement) * A = [P*A*Na] / √[2πMRT] ….. (i)
From the above formula in (i), we can write
Rate of effusion ∝ [A / √M]
∴ r1/r2 = [A1/A2] * √[M2/M1]
⇒ r1/r2 = ½ * √[32/2]
⇒ r1/r2 = 4/2 = 2 / 1
Thus, the ratio of the rate of effusion will be 2:1.
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