Two isomeric alkynes A and B have molecular formula C8H14 A
on treatment with ammoniacal AgNO3 solution forms a white
precipitate while B on similar treatment formed no precipitate.
Also both A and B are chiral and hydrogenation of either A or B
with H/Pt gives the same achiral hydrocarbon C(C3H18).
Treatment of A with HgSO4/H2SO4 (aq) gives D(C3H160) as
major product while similar treatment of B, mixture of D and E
in comparable amounts are formed.
The structures of A and B are respectively
Answers
Answer:
This discussion on Passage IITwo isomeric alkynes A and B have molecular formula C8H14 A on treatment with ammoniacal AgNO3 solution forms a white precipitate while B on similar treatment formed no precipitate. Also both A and B are chiral and hydrogenation of either A or B with H2/Pt gives the same achiral hydrocarbon C(C8H18). Treatment of A with HgSO4 /H2SO4 (aq) gives D(C8H16O) a s major product while sim ilar treatment of B, mixture of D and Ein comparable amounts are formed.Q.What is true regarding A and B?a)Both will evolve H2(g) on heating with Na metalb)A will give same product with either HgSO4 /H2SO4 or B2H6/H2O2/NaOHc)B will give same product with either HgSO4/H2SO4 or B2H6/H2O2/NaOHd)Both will produce a stereoisomers with Lindlar’s catalystCorrect answer is option 'C,D'. Can you explain this answer? is done on EduRev Study Group by Class 11 Students. The Questions and Answers of Passage IITwo isomeric alkynes A and B have molecular formula C8H14 A on treatment with ammoniacal AgNO3 solution forms a white precipitate while B on similar treatment formed no precipitate. Also both A and B are chiral and hydrogenation of either A or B with H2/Pt gives the same achiral hydrocarbon C(C8H18). Treatment of A with HgSO4 /H2SO4 (aq) gives D(C8H16O) a s major product while sim ilar treatment of B, mixture of D and Ein comparable amounts are formed.Q.What is true regarding A and B?a)Both will evolve H2(g) on heating with Na metalb)A will give same product with either HgSO4 /H2SO4 or B2H6/H2O2/NaOHc)B will give same product with either HgSO4/H2SO4 or B2H6/H2O2/NaOHd)Both will produce a stereoisomers with Lindlar’s catalystCorrect answer is option 'C,D'. Can you explain this answer? are solved by group of students and teacher of Class 11, which is also the largest student community of Class 11. If the answer is not available please wait for a while and a community member will probably answer this soon. You can study other questions, MCQs, videos and tests for Class 11 on EduRev and even discuss your questions like Passage IITwo isomeric alkynes A and B have molecular formula C8H14 A on treatment with ammoniacal AgNO3 solution forms a white precipitate while B on similar treatment formed no precipitate. Also both A and B are chiral and hydrogenation of either A or B with H2/Pt gives the same achiral hydrocarbon C(C8H18). Treatment of A with HgSO4 /H2SO4 (aq) gives D(C8H16O) a s major product while sim ilar treatment of B, mixture of D and Ein comparable amounts are formed.Q.What is true regarding A and B?a)Both will evolve H2(g) on heating with Na metalb)A will give same product with either HgSO4 /H2SO4 or B2H6/H2O2/NaOHc)B will give same product with either HgSO4/H2SO4 or B2H6/H2O2/NaOHd)Both will produce a stereoisomers with Lindlar’s catalystCorrect answer is option 'C,D'. Can you explain this answer? over here on EduRev! Apart from being the largest Class 11 community, EduRev has the largest solved Question bank for Class 11.