two samples p and q of carbon dioxide obtained from two different reactions. the details about their composition are as follows. sample p mass 449 mass of constituent carbon : 12g mass of constituent oxygen : 32g sample q mass 2.2g mass of constituent carbon : 0.6g mass of constituent oxygen : 1.6 which law of chemical combination does this prove explain
Answers
Answer:
Determining Empirical and Molecular Formulas
LEARNING OBJECTIVES
By the end of this section, you will be able to:
Compute the percent composition of a compound
Determine the empirical formula of a compound
Determine the molecular formula of a compound
In the previous section, we discussed the relationship between the bulk mass of a substance and the number of atoms or molecules it contains (moles). Given the chemical formula of the substance, we were able to determine the amount of the substance (moles) from its mass, and vice versa. But what if the chemical formula of a substance is unknown? In this section, we will explore how to apply these very same principles in order to derive the chemical formulas of unknown substances from experimental mass measurements.
Percent Composition
The elemental makeup of a compound defines its chemical identity, and chemical formulas are the most succinct way of representing this elemental makeup. When a compound’s formula is unknown, measuring the mass of each of its constituent elements is often the first step in the process of determining the formula experimentally. The results of these measurements permit the calculation of the compound’s percent composition, defined as the percentage by mass of each element in the compound. For example, consider a gaseous compound composed solely of carbon and hydrogen. The percent composition of this compound could be represented as follows:
\displaystyle \%\text{H}=\frac{\text{mass H}}{\text{mass compound}}\times 100\%%H=
mass compound
mass H
×100%
\displaystyle \%\text{C}=\frac{\text{mass C}}{\text{mass compound}}\times 100\%%C=
mass compound
mass C
×100%
If analysis of a 10.0-g sample of this gas showed it to contain 2.5 g H and 7.5 g C, the percent composition would be calculated to be 25% H and 75% C:
\displaystyle \%\text{H}=\frac{2.5\text{g H}}{10.0\text{g compound}}\times 100\%=25\%%H=
10.0g compound
2.5g H
×100%=25%
\displaystyle \%\text{C}=\frac{7.5\text{g C}}{10.0\text{g compound}}\times 100\%=75\%%C=
10.0g compound
7.5g C
×100%=75%