Under which of the following conditions is the
relation, DeltaH = DeltaE + P DeltaV valid for a system
a) constant pressure
b) constant temperature
c) constant temperature and pressure
d) constant temperature, pressure and composition
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Answer:
a. constant pressure
Explanation:
According to the first law of thermodynamics
∆E=∆Q-P∆V
∆Q=∆E+P∆V
comparing the equation given
∆Q=∆H
nC∆t=n(Cp)∆t
C=Cp
happens only in const pressure process
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