use of titanium silicate (ts-1) in organic tranceformetion
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A new procedure for the synthesis of titanium silicate-1 (TS-1) with high Ti(Si+Ti) ratios is being reported. The rationale for the method adopted and the reasons for the incorporation of more Ti (than reported by earlier workers) are discussed based on liquid-phase n.m.r. studies of the precursors and reaction mixture. The influence of various synthesis parameters like temperature, SiO2 TiO2 ,Dh SiO2 and H2O SiO2, ratios, the silica source, and nature of organic additives on the synthesis of TS-1 is discussed. The TS-1 samples have been characterized by XRD, i.r. t.g./d.t.a., and SEM.
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