Chemistry, asked by rishabh204, 1 year ago

Using Bohr atomic model, drive expression for calculating the radius of orbits in He+. Using this expression, calculate the radius of fourth orbit of He+ ion.

Answers

Answered by abhi178
10
according to bohr theory
radius of orbit(rn)= 0.529 (n^2/z) A
now
radius of 4th orbit of He+=0.529 (16/2)
= 0.529x8A
=4.232A

malikprachi: can you please derive the expression of radius of orbits of helium
Answered by BarrettArcher
1

Answer : The radius of fourth orbit of hydrogen like atom (He^+) is, 423.2pm

Solution :

Derivation for calaculating the radius of orbits of hydrogen atom and hydrogen like atom, He^+.

According to the Bohr's theory of hydrogen like atom, the electrons move around the nucleus in a stationary circular orbit.

Two forces are applied which are attractive forces and centripetal forces.

Attractive force : F_A=\frac{Ze^2}{4\pi \epsilon_or^2}   .......(1)

Centripetal force : F_c=\frac{mv^2}{r}     ........(2)

Now for electrons to remain stationary at a position,

\frac{mv^2}{r}=\frac{Ze^2}{4\pi \epsilon_or^2}

mv^2=\frac{Ze^2}{4\pi \epsilon_or}      .........(3)

Now from the angular momentum condition,

mvr=\frac{nh}{2\pi}

or,

mv^2=\frac{n^2h^2}{4\pi^2r^2m}     ..........(4)

Now equating equation 4 in 3, we get

r_n=\frac{n^2\times 0.529A^o}{Z}

r_n=\frac{n^2\times 52.9}{Z}   (in pm)

Formula used for the radius of the n^{th} orbit will be,

r_n=\frac{n^2\times 52.9}{Z}   (in pm)

where,

r_n = radius of n^{th} orbit

n = number of orbit  = 4

Z = atomic number  of helium = 2

Now we have to calculate the radius of fourth orbit of hydrogen like atom (He^+)

Radius of first orbit of (He^+) :

r_4=\frac{(4)^2\times 52.9}{2}=423.2pm

Therefore, the radius of fourth orbit of hydrogen like atom (He^+) is, 423.2pm

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