(v) Construct a galvanic cell from the electrodes
CO3+ Co and Mn2+ | Mn Ec=
=182 V, E= -113 V.
Calculate E
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Given:
Cell potential of Co=182V
Cell potential of Mn = -113V
To find:
Cell potential and cell representation.
Solution:
formula used for finding cell potential,
cell potential of cell = cell potential of cathode - cell potential of anode
electrode reactions are:
at anode: 3×( Mn(s) → Mn²⁺(aq) + 2e⁻ )
at cathode: 2×( Co³⁺(aq) + 3e⁻ → Co(s) )
anode representation is Mn(s)IMn²⁺(aq)
and cathode representation is Co³⁺(aq)|Co(s)
so, the overall galvanic cell representation is,
Mn(s)|Mn²⁺(aq)║Co³⁺(aq)|Co(s)
therefore, electrode potential will be calculated as-
E = E at cathode - E at anode
E = E of Mn²⁺|Mn - E at Co³⁺|Co
E = 182V - (- 113V)
E = 295V
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