Van der Waals interactions result when
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These interactions can be temporary when a non-polar molecule's electrons accumulate temporarily on one side of the molecule. This creates a positiveand negative charge on the molecule and the attractive force between molecules resulting from this are a type of Van der Waals force called London dispersion forces.
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The van der Waals constant 'a' represents the magnitude of intermolecular forces of attraction and the Van der Waals constant 'b' represents the effective size of the molecules.
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