Very short Ouestion answer What difference in the property off two miscible liquid enables there are separated by fractional distillation?
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Several properties can be the basis for separation, however, traditionally it is differences in boiling point. You separate by distillation. However some compounds such as ethanol and water form an azeotrope. For water:ethanol benzene can be added to “break” the azeotrope or water can be removed by electrolysis
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