Question

Violations of Onsager reciprocity?

Answer 1

Hey mate ^_^

The modern statement of Onsager reciprocity is that the linear-response transport coefficient matrix, when transposed, is equal to that of the time-reversed system (reversed external magnetic field, reversed internal magnetic order, reversed Coriolis forces, and so on).....

Many consider this to be the fourth law of thermodynamics.....


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Answer 2

Hello mate here is your answer.

When the full relaxation matrix possesses Onsager-Casimir symmetry, the reduced matrix has contributions that violate this symmetry.The occurrence of such a symmetry violation is demonstrated for a simple example.

Hope it helps you.