Question

volatile loquid is boiled by the warm surface water​

Answer 1

Is your question "Does volatile liquid boil from the surface?"?

No, they don't. The atoms are just flying off from the surface.

Explanation

Surface of volatile liquid is not boiling.

What makes a liquid so volatile is the weak connection between molecules.

The molecules on the surface is moving.

But the connection is too weak to hold themselves from vaporizing.

So they just fly off.