what are conjugated diketones
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The word "conjugation" is derived from a Latin word that means "to link together". In organic chemistry terms, it is used to describe the situation that occurs when π systems (e.g. double bonds) are "linked together". An "isolated" π (pi) system exists only between a single pair of adjacent atoms (e.g. C=C)
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A double single conjugated organic compound known as a conjugated diketone contains two ketone groups.
Conjugated ketone:
- An aromatic molecule is made up of a series of covalent bonds with particular properties, such as a delocalized conjugated system of electrons and an arrangement of single and double bonds that alternate.
- All the atoms should be in the same plane and the structure should be coplanar.
- It should adhere to Huckel's rule, which calls for several delocalized electrons.
- Electrons are delocalized with the alternate single and double bond in a conjugated system.
- The system may also include lone pairs.
- The carbon of the carbonyl group is directly connected to a C=C unit in a conjugated ketone.
Non-conjugated ketones:
- Ketones without a conjugation No C=C units come into contact with the carbonyl group.
- While CH2=CHCH2C(O)CH3 would be non-conjugate.
- Because the Carbon atoms making the double bond do not directly contact the carbonyl group, CH2=CHCH2C(O)CH3 is a simple conjugated ketone.
- Due to the ring's presence of electrons, which violates Huckel's criterion, the compound does not appear to be aromatic based on its structure.
- However, a resonant structure that is aromatic is created upon resonance with other atoms.
- Because a substance might be aromatic in more than one way, it is important not to judge its aromaticity solely by its appearance.
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