What are different process for manufacturing washing soda?
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1. CO2 reacts with ammonia gives ammonium carbonate.
2NH3 ➕ CO2 ➕ H2O ----»(NH4)2CO3
2.Ammonium carbonate further reacts with CO2 to form ammonium bicarbonate.
(NH4)2CO3 ➕ CO2 ➕ H2O ----» 2NH4HCO3
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3. Ammonium bicarbonate then react with NaCl to form sodium bicarbonate.
NH4HCO3 + NaCl -- NaHCO3 + NH4Cl
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1. CO2 reacts with ammonia gives ammonium carbonate.
2NH3 ➕ CO2 ➕ H2O ----»(NH4)2CO3
2.Ammonium carbonate further reacts with CO2 to form ammonium bicarbonate.
(NH4)2CO3 ➕ CO2 ➕ H2O ----» 2NH4HCO3
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3. Ammonium bicarbonate then react with NaCl to form sodium bicarbonate.
NH4HCO3 + NaCl -- NaHCO3 + NH4Cl
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For Manufacturing of Washing Soda, the Solvay process is extensively used for industrial preparation of sodium carbonate (soda ash).
1. CO2 reacts with ammonia to form ammonium carbonate.
2NH3 + CO2 + H2O --> (NH4)2CO3
2.Ammonium carbonate further reacts with CO2 to form ammonium bicarbonate.
(NH4)2CO3 + CO2 + H2O -- >2NH4HCO3 (aq.)
3. Ammonium bicarbonate then react with NaCl to form sodium bicarbonate.
NH4HCO3 + NaCl --> NaHCO3 + NH4Cl
4.Dry sodium bicarbonate is then heated to give anhydrous sodium carbonate. Carbon dioxide is then again recirculated.
2NaHCO3 --> Na2CO3 + CO2 + H2O
1. CO2 reacts with ammonia to form ammonium carbonate.
2NH3 + CO2 + H2O --> (NH4)2CO3
2.Ammonium carbonate further reacts with CO2 to form ammonium bicarbonate.
(NH4)2CO3 + CO2 + H2O -- >2NH4HCO3 (aq.)
3. Ammonium bicarbonate then react with NaCl to form sodium bicarbonate.
NH4HCO3 + NaCl --> NaHCO3 + NH4Cl
4.Dry sodium bicarbonate is then heated to give anhydrous sodium carbonate. Carbon dioxide is then again recirculated.
2NaHCO3 --> Na2CO3 + CO2 + H2O
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