What are pseudo first order reactions ? Give an example
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the order of reaction now becomes one, that is the reaction is now first order reaction. Such reactions are called pseudo-first order reactions. Another example of pseudo first-order reaction is the inversion of cane sugar.
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→ Pseudo First Order Reaction :
A chemical reaction between two substances when one reactant is present in excess quantity .
Ex ; Hydrolysis of Ethyl Acetate -
- If At time t=0 : 0.01 mol 10 mol 0 mol 0 mol
- and, at time t : 0 mol 9.99 mol 0.01 mol 0.01 mol
-> [H_{2} O]_{t=0 } ≅ [H_{2} O]_{t}
; mean that concentration of H_{2} O does not change . So it ca not change the rate . [H_{2} O] = constant
k'[H_{2} O] = constant
= k
-> Rate of reaction = k'[H_{2} O]
Rate of reaction = k[CH_{3}COOC_{2}H_{5} ] -> It indicates order kinetics .
hopr it helpes .... tq
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