Question

What are the limitations of Henry's law?

Answer 1

In chemistry, Henry's law is a gas law that states that the amount of dissolved gas is proportional to its partial pressure in the gas phase. The proportionality factor is called the Henry's law constant. It was formulated by the English chemist William Henry, who studied the topic in the early 19th century. In his publication about the quantity of gases absorbed by water,[1] he described the results of his experiments:
..."water takes up, of gas condensed by one, two, or more additional atmospheres, a quantity which, ordinarily compressed, would be equal to twice, thrice, &c. the volume absorbed under the common pressure of the atmosphere."An example where Henry's law is at play is in the depth-dependent dissolution of oxygen and nitrogen in the blood of underwater divers that changes during decompression, leading to decompression sickness.[not verified in body] An everyday example is given by one's experience with carbonated soft drinks, which contain dissolved carbon dioxide.[not verified in body] Before opening, the gas above the drink in its container is almost pure carbon dioxide, at a pressure higher than atmospheric pressure. After the bottle is opened, this gas escapes, moving the partial pressure of carbon dioxide above the liquid to be much lower, resulting in degassing as the dissolved carbon dioxide comes out of solution.

Answer 2

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