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Answered by freefire10032
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Deterioration factors and their control

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A summary of overall deterioration reactions in fruits and vegetables is presented below.

3.1 Enzymic changes

Enzymes which are endogenous to plant tissues can have undesirable or desirable consequences. Examples involving endogenous enzymes include a) the post-harvest senescence and spoilage of fruit and vegetables; b) oxidation of phenolic substances in plant tissues by phenolase (leading to browning); c) sugar - starch conversion in plant tissues by amylases; d) post-harvest demethylation of pectic substances in plant tissues (leading to softening of plant tissues during ripening, and firming of plant tissues during processing).

The major factors useful in controlling enzyme activity are: temperature, water activity, pH, chemicals which can inhibit enzyme action, alteration of substrates, alteration of products and pre-processing control.

3.2 Chemical changes

3.2.1 Sensory quality

The two major chemical changes which occur during the processing and storage of foods and lead to a deterioration in sensory quality are lipid oxidation and non-enzymatic browning. Chemical reactions are also responsible for changes in the colour and flavour of foods during processing and storage.

3.2.1.1 Lipid oxidation rate and course of reaction is influenced by light, local oxygen concentration, high temperature, the presence of catalysts (generally transition metals such as iron and copper) and water activity. Control of these factors can significantly reduce the extent of lipid oxidation in foods.

3.2.1.2 Non-enzymic browning is one of the major causes of deterioration which occurs during storage of dried and concentrated foods. The non-enzymic browning, or Maillard reaction, can be divided into three stages: a) early Maillard reactions which are chemically well-defined steps without browning; b) advanced Maillard reactions which lead to the formation of volatile or soluble substances; and c) final Maillard reactions leading to insoluble brown polymers.

3.2.1.3 Colour changes

Chlorophylls. Almost any type of food processing or storage causes some deterioration of the chlorophyll pigments. Phenophytinisation (with consequent formation of a dull olivebrown phenophytin) is the major change; this reaction is accelerated by heat and is acid catalysed.

Other reactions are also possible. For example, dehydrated products such as green peas and beans packed in clear glass containers undergo photo-oxidation and loss of desirable colour.

Anthocyanins. These are a group of more than 150 reddish water-soluble pigments that are very widespread in the plant kingdom. The rate of anthocyanin destruction is pH dependent, being greater at higher pH values. Of interest from a packaging point of view is the ability of some anthocyanins to form complexes with metals such as Al, Fe, Cu and Sn.

These complexes generally result in a change in the colour of the pigment (for example, red sour cherries react with tin to form a purple complex) and are therefore undesirable. Since metal packaging materials such as cans could be sources of these metals, they are usually coated with special organic linings to avoid these undesirable reactions.

Carotenoids. The carotenoids are a group of mainly lipid soluble compounds responsible for many of the yellow and red colours of plant and animal products. The main cause of carotenoid degradation in foods is oxidation. The mechanism of oxidation in processed foods is complex and depends on many factors. The pigments may auto-oxidise by reaction with atmospheric oxygen at rates dependent on light, heat and the presence of pro- and antioxidants.

3.2.1.4 Flavour changes

In fruit and vegetables, enzymically generated compounds derived from long-chain fatty acids play an extremely important role in the formation of characteristic flavours. In addition, these types of reactions can lead to significant off-flavours. Enzyme-induced oxidative breakdown of unsaturated fatty acids occurs extensively in plant tissues and this yield characteristic aromas associated with some ripening fruits and disrupted tissues.

The permeability of packaging materials is of importance in retaining desirable volatile components within packages, or in permitting undesirable components to permeate through the package from the ambient atmosphere.

Answered by sardarg41
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Answer:

Deterioration factors and their control

Contents - Previous - Next

A summary of overall deterioration reactions in fruits and vegetables is presented below.

3.1 Enzymic changes

Enzymes which are endogenous to plant tissues can have undesirable or desirable consequences. Examples involving endogenous enzymes include a) the post-harvest senescence and spoilage of fruit and vegetables; b) oxidation of phenolic substances in plant tissues by phenolase (leading to browning); c) sugar - starch conversion in plant tissues by amylases; d) post-harvest demethylation of pectic substances in plant tissues (leading to softening of plant tissues during ripening, and firming of plant tissues during processing).

The major factors useful in controlling enzyme activity are: temperature, water activity, pH, chemicals which can inhibit enzyme action, alteration of substrates, alteration of products and pre-processing control.

3.2 Chemical changes

3.2.1 Sensory quality

The two major chemical changes which occur during the processing and storage of foods and lead to a deterioration in sensory quality are lipid oxidation and non-enzymatic browning. Chemical reactions are also responsible for changes in the colour and flavour of foods during processing and storage.

3.2.1.1 Lipid oxidation rate and course of reaction is influenced by light, local oxygen concentration, high temperature, the presence of catalysts (generally transition metals such as iron and copper) and water activity. Control of these factors can significantly reduce the extent of lipid oxidation in foods.

3.2.1.2 Non-enzymic browning is one of the major causes of deterioration which occurs during storage of dried and concentrated foods. The non-enzymic browning, or Maillard reaction, can be divided into three stages: a) early Maillard reactions which are chemically well-defined steps without browning; b) advanced Maillard reactions which lead to the formation of volatile or soluble substances; and c) final Maillard reactions leading to insoluble brown polymers.

3.2.1.3 Colour changes

Chlorophylls. Almost any type of food processing or storage causes some deterioration of the chlorophyll pigments. Phenophytinisation (with consequent formation of a dull olivebrown phenophytin) is the major change; this reaction is accelerated by heat and is acid catalysed.

Other reactions are also possible. For example, dehydrated products such as green peas and beans packed in clear glass containers undergo photo-oxidation and loss of desirable colour.

Anthocyanins. These are a group of more than 150 reddish water-soluble pigments that are very widespread in the plant kingdom. The rate of anthocyanin destruction is pH dependent, being greater at higher pH values. Of interest from a packaging point of view is the ability of some anthocyanins to form complexes with metals such as Al, Fe, Cu and Sn.

These complexes generally result in a change in the colour of the pigment (for example, red sour cherries react with tin to form a purple complex) and are therefore undesirable. Since metal packaging materials such as cans could be sources of these metals, they are usually coated with special organic linings to avoid these undesirable reactions.

Carotenoids. The carotenoids are a group of mainly lipid soluble compounds responsible for many of the yellow and red colours of plant and animal products. The main cause of carotenoid degradation in foods is oxidation. The mechanism of oxidation in processed foods is complex and depends on many factors. The pigments may auto-oxidise by reaction with atmospheric oxygen at rates dependent on light, heat and the presence of pro- and antioxidants.

3.2.1.4 Flavour changes

In fruit and vegetables, enzymically generated compounds derived from long-chain fatty acids play an extremely important role in the formation of characteristic flavours. In addition, these types of reactions can lead to significant off-flavours. Enzyme-induced oxidative breakdown of unsaturated fatty ac

Explanation:

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