what are the products of kolbe electrolysis of potassium malonate?
Answers
Explanation:
the kolbe electrolysis or kolbe reaction is an organic reaction named after hermann kolbe. the kolbe reaction is formally a decarboxylative dimerisation of two carboxylic acids (or carboxylate ions) the overall general reaction is:
electrólisis de Kolbe png
if a mixture of two different carboxylates are used, all combinations of them are generally seen as the organic product structures:
3 r1coo− + 3 r2coo− → r1−r1 + r1−r2 + r2−r2 + 6 co2 + 6 e−
the reaction mechanism involves a two-stage radical process: electrochemical decarboxylation gives a radical intermediate, then two such intermediates combine to form a covalent bond. as an example, electrolysis of acetic acid yields ethane and carbon dioxide:
Answer:
The Kolbe electrolysis involves the formation of symmetrical hydrocarbons through the coupling of radicals generated from carboxylic acid at an anode via electrolysis. ... This reaction is useful for the preparation of hydrocarbons