What determines an emission wavelength after being pumped?
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When electrons go from the excited state to the ground state (see the section below entitled Molecular Explanation), there is a loss of vibrational energy. As a result, the emission spectrum is shifted to longer wavelengths than the excitationspectrum (wavelength varies inversely to radiation energy).
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emission wavelength; the effect of this process on laser emission is not negligible, due to the high
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