What happens if the two bulky groups eclipse in the newman conformation?
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Alkanes are capable of several different conformational isomers; isomers ... Newman, Newman WebMO ... Starting at a dihedral angle of zero, the two methyl groups are overlapping ...
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Comparing 1, 3 and 5, we see that 1 has two “bad” gauche interactions, whereas 3 and 5 have only one gauche interaction; thus 3 and 5 are both equally stable, and they are the most stable conformations for 2-methylbutane
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