what happens when Benzene reacts with methanoyl chloride in presence of Lewis acid
Answers
Explanation:
We get Acetophenone (C6H5COCH3) as the major product.
Now lets see the mechanism :)
AlCl3 is considered to be a Lewis Acid or in simpler words an “electron hungry species”. So, when it sees Acetyl Chloride (CH3COCl) it extracts the -Cl minus from the latter and itself gets transformed into AlCl4 minus. Now it is quite stable because his hunger has been satisfied.
Now it leaves behind an electrophile -COCH3 minus. We all know that benzene undergoes aromatic electrophilic substitution reactions. As a result the other electrophile gets attached to the benzene ring thereby forming Acetophenone (C6H5COCH3).
AlCl3 is also a catalyst in this reaction because it gives off its Cl minus after the end of reaction and HCl is formed as bye product.
The most reactive substance containing an acyl group is an acyl chloride (also known as an acid chloride). These have the general formula RCOCl. Benzene is treated with a mixture of ethanoyl chloride, CH3COCl, and aluminium chloride as the catalyst. A ketone called phenylethanone is formed.