What is a markownikoff's rule explain with an example?
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➡️Markovnikov's rule (Markovnikov addition): In an addition reaction of a protic acid HX (hydrogen chloride, hydrogen bromide, or hydrogen iodide) to an alkene or alkyne, the hydrogen atom of HX becomes bonded to the carbon atom that had the greatest number of hydrogen atoms in the starting alkene or alkyne.
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The Markovnikov’s rule predicts the outcome of addition reaction carried out on addition of protic acid HX to an asymmetric alkene, also called hydrohalogenation (under standard conditions). It was formulated by Vladimr Markovnikov in 1865
Explanation of the Markovnikov’s Rule Mechanism with a Simple Example
When a protic acid HX (X = Cl, Br, I) is added to an asymmetrically substituted alkene, addition of acidic hydrogen takes place at the less substituted carbon atom of the double bond, while halide X is added to the more alkyl substituted carbon atom. In other words, hydrogen is added to the carbon atom with more number of hydrogen atoms attached to it and halide is added to the carbon atom with least number of hydrogen atoms
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