what is ambident nucleophile..??
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An ambident nucleophile is an anionic nucleophile whose negative charge is delocalized by resonance over two unlike atoms or over two like but non-equivalent atoms. The most common ambident nucleophiles are enolate ions. For example, the resonance forms of acetone enolate
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Ambident nucleophiles are those with 2 nucleophile centres. For example cyanide act as ambident nucleophile.
There are 2 nucleophile centres, at carbon and nitrogen in cyanide ion (C=N:). They can react through either of these centres. Depending on the reagent and the reaction conditions, the reaction may take place predominantly at one of these centres.
Examples are C = N: (reagent KCN, NaCN) etc.
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