Chemistry, asked by saman7869, 1 year ago

what is defination of third law of thermodynamic ?

Answers

Answered by rowdy1826
4

Answer:

The third law of thermodynamics states that the entropy of a system at absolute zero is a well-defined constant. This is because a system at zero temperature exists in its ground state, so that its entropy is determined only by the degeneracy of the ground state.

Answered by ameychand2207
0

Explanation:

The Third Law of Thermodynamics is concerned with the limiting behavior of systems as the temperature approaches absolute zero. Most thermodynamics calculations use only entropy differences, so the zero point of the entropy scale is often not important. However, we discuss the Third Law for purposes of completeness because it describes the condition of zero entropy.

The Third Law states, “The entropy of a perfect crystal is zero when the temperature of the crystal is equal to absolute zero (0 K).” According to Purdue University, “The crystal must be perfect, or else there will be some inherent disorder. It also must be at 0 K; otherwise there will be thermal motion within the crystal, which leads to disorder.”

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