what is different between system and surrounding
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in Chemistry. The system consists of those molecules which are reacting. The surroundings are everything else; the rest of the universe. For example, say the above reaction is happening in gas phase; then the walls of the container are part of the surroundings.
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A system, as it is defined in physics or chemistry, is nothing more than a collection of objects (or smaller systems) that can be identified. Usually, the word system refers to a collection that makes thinking about a problem more convenient. The surrounding is everything else that is not the system defined.
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