What is Galvanic cell
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Explanation:
A galvanic cell or voltaic cell, named after the scientists Luigi Galvani and Alessandro Volta, respectively, is an electrochemical cell in which an electric current is generated from spontaneous redox reactions.
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QuestioN :-
What is Galvanic Cell ?
ANsWeR :-
Galvanic cell (or) voltaic cell is an electrochemical cell that makes use of chemical reactions to generate electrical energy.
Principle of Galvanic Cell :-
- Electric work done by a galvanic cell is mainly due to the Gibbs energy of spontaneous redox reaction in the voltaic cell.
- It generally consists of two half cells and a salt bridge.
- Each half cell further consists of a metallic electrode dipped into an electrolyte.
- These two half-cells are connected to a voltmeter and a switch externally with the help of metallic wires.
- In some cases, when both the electrodes are dipped in the same electrolyte, a salt bridge is not required.
Parts of Galvanic Cell :-
- Anode
- Cathode
- Salt Bridge
- Half - Cells
- External Circuit
- Load
How Galvanic Cell Works :-
- In a galvanic cell, when an electrode is exposed to the electrolyte at the electrode-electrolyte interface, the atoms of the metal electrode have a tendency to generate ions in the electrolyte solution leaving behind the electrons at the electrode. Thus, making the metal electrode negatively charged.
- While at the same time metal ions in the electrolyte solution too, have a tendency to deposit on a metal electrode. Thus, making the electrode positively charged.
- Under equilibrium condition, charge separation is observed and depending on the tendencies of two opposing reactions, the electrode can be positively or negatively charged. Hence, a potential difference is developed between the electrode and electrolyte.
- This potential difference is known as electrode potential.
- Out of two electrodes, the electrode at which oxidation takes place is called anode while the electrode at which reduction takes place is called cathode.
- The anode has a negative potential with respect to the solution while the cathode has a positive potential with respect to the solution.
- Thus, a potential difference develops between two electrodes of the galvanic cell. This potential difference is known as cell potential.
- When no current is drawn from the galvanic cell, cell potential is known as the electromotive force of the galvanic cell.
- When the switch is set on, due to the potential difference, electrons flow from the negative electrode to the positive electrode.
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