Chemistry, asked by ashish6269126543, 1 year ago

What is inert pair effect​

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Answered by shalin1853
4

The term inert pair effect is often used in relation to the increasing stability of oxidation states that are two less than the group valency for the heavier elements of groups 13, 14, 15 and 16. The term "inert pair" was first proposed by Nevil Sidgwick in 1927.[1] The name suggests that the outermost s electrons are more tightly bound to the nucleus in these atoms, and therefore more difficult to ionize or share.

For example, the p-block elements of the 4th, 5th and 6th period come after d-block elements, but the electrons present in the intervening d- (and f-) orbitals do not effectively shield the s-electrons of the valence shell. As a result, the inert pair of ns electrons remains more tightly held by the nucleus and hence participates less in bond formation .

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Answered by nikitalohat703
1

On moving down the group, ns electrons do not take part in chemical bonding due to weak shielding by inner d and f subshell electrons, this phenomenon is known as inert pair effect.


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