what is iodoform test in alcohols and aldehyde and ketones?
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- IODOFORM TEST is the main test used to distinguish METHY ALCOHAL from ETHYL ALCOHAL..
- IDOFORM TEST is also used for distinguishing METHYL KETONES from other ketones
- It can be used to distinguish ACETALDEHYDE from other ALDEHYDES ...
Explanation:
IDOFORM TEST :-
THE HALOFORM REACTION USING IDODINE
AND IAQUEOUS SODIUM HYDROXIDE IS
CALLED THE IDOFORM TEST ...
IT result in the formation of water insoluble IDOFORM which is a YELLOW SOLID...
ETHANOL :
CH3CH20H +4I2 +6NaOH →
CHI3 + HCOONA + 5 NaI = 5H20
IDOFORM + SODIUM FORMATE
- Methanol is not able to give this reaction BECAUSE Only SECONDARY ALCHOAL containing the HYDROXL GROUP on the second Carbon atom can undergo this reaction ........
ACETALDEHYDE :
CH3COOH + 3I2+ 4NaOH → CHI3 + HCOONa + 3NaI + 3H20
ACETONE :
CH3COCH3 + 3I2 + 4NaOH → CH13 +CH3COONA + 3 NaI + 3H20 SODIUM ACETATE
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