what is isomerisation.......how is it different from average reaction
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In chemistry isomerization (also isomerisation) is the process by which one molecule is transformed into another molecule which has exactly the same atoms, but the atoms have a different arrangement e.g. A-B-C → B-A-C (these related molecules are known as isomers).
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The process is particularly useful in enhancing the octane rating of petrol, as branched alkanes burn more efficiently in a car engine than straight-chain alkanes.
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In chemistry isomerization (also isomerisation) is the process by which one molecule is transformed into another molecule which has exactly the same atoms, but the atoms have a different arrangement e.g. A-B-C → B-A-C (these related molecules are known as isomers [1]). In some molecules and under some conditions, isomerization occurs spontaneously. Many isomers are roughly equal in bond energy, and so exist in roughly equal amounts, provided that they can interconvert somewhat freely; that is, the energy barrier between the two isomers is not too high. When the isomerization occurs intramolecularly it is considered a rearrangement reaction.
Isomerization of vinyl norbornene gives the commercially important monomer ethylidene norbornene.
The energy difference between two isomers is called "isomerization energy". Isomerizations with low energy difference both experimental and computational (in parentheses) are endothermic trans-cis isomerization of 2-butene with 2.6 (1.2) kcal/mol, cracking of isopentane to n-pentane with 3.6 (4.0) kcal/mol or conversion of trans-2-butene to 1-butene with 2.6 (2.4) kcal/mol.[2]
Isomerization of vinyl norbornene gives the commercially important monomer ethylidene norbornene.
The energy difference between two isomers is called "isomerization energy". Isomerizations with low energy difference both experimental and computational (in parentheses) are endothermic trans-cis isomerization of 2-butene with 2.6 (1.2) kcal/mol, cracking of isopentane to n-pentane with 3.6 (4.0) kcal/mol or conversion of trans-2-butene to 1-butene with 2.6 (2.4) kcal/mol.[2]
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