what is lanthanide contraction give one off .
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- Lanthanide contraction is the gradual decrease in the atomic and ionic size of lanthanoids with an increase in atomic number.
Causes of lanthanide contraction:
- With an increase in the atomic number, the positive charge on nucleus increases by one unit and one more electron enters same 4f subshell.
- The electrons in 4f subshell imperfectly shield each other. Shielding in a 4f subshell is lesser than in d subshell..
- With the increase in nuclear charge, the valence shell is pulled slightly towards the nucleus. This causes lanthanide contraction.
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