What is meant by positive and negative deviations from Raoult's law and how is the sign of ∆mixH related to positive e and negative deviations from Raoult's law?
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According to Raoult's law, the partial vapor pressure of each component in any solution is directly proportional to its mole fraction. ... If the vapor pressure is higher then solution is said to exhibit positive deviation, And if the vapour pressure is lower than the solution than it said to be negative deviation.
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