What is meant by solvation energy ?
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The energy of solvation is the amount of energy associated with dissolving a solute in a solvent. If it is a positive number, the dissolving process is endothermic; if it is negative, it's exothermic.
In the process of solvation, ions are surrounded by concentric shells of solvent. Solvation is the process of reorganizing solvent and solute molecules into solvation complexes. Solvation involves bond formation, hydrogen bonding, and van der Waals forces. The solvation of a solute of water is called hydration.
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The solvation energy (change in Gibbs free energy) is the change in enthalpy minus the product of temperature (in Kelvin) times the change in entropy. Gases have a negative entropy of solution, due to the decrease in gaseous volume as gas dissolves.
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