Chemistry, asked by atifbhat07, 1 day ago

What is Nernst equation. How can Nernst equation be applied in calculating the equilibrium constant for any cell reaction?

Answers

Answered by singnshaurya
0

Explanation:

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Answered by devikachandran18
1

Answer:

Nernst equation is an equation in electrochemistry that enables the determination of cell potential under non-standard conditions.

Equilibrium constant for any cell reaction can be calculated using Nernst equation by the following formula :

log K _{eq} = \frac{nE^{0} }{0.0592}

Explanation:

Nernst equation relates the reduction potential of a reaction (half-cell or full cell reaction) to the standard electrode potential, temperature, and activities of the chemical species that is undergoing reduction and oxidation.

E = E° - \frac{2.303 RT}{nF} log_{10} Q

E - Cell potential

E° - Standard cell potential

R - Gas constant

T - Temperature

n  - Number of electrons transferred in the reaction (from balanced reaction)

F - Faraday constant (96,500 C/mol)

Q - Reaction quotient

At standard temperature T = 298 K, \frac{2.303 RT}{F} = 0.0592 V

Then the Nernst equation can ne rewritten as :

E = E° - \frac{0.0592}{n} log_{10} Q

At equilibrium, E = 0 and Q = K_{eq}

where K_{eq} is the equilibrium constant.

Equation can be rearranged to obtain the following relation:

log K_{eq} = \frac{nE^{0} }{0.0592}

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