What is Nernst equation. How can Nernst equation be applied in calculating the equilibrium constant for any cell reaction?
Answers
Explanation:
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Answer:
Nernst equation is an equation in electrochemistry that enables the determination of cell potential under non-standard conditions.
Equilibrium constant for any cell reaction can be calculated using Nernst equation by the following formula :
=
Explanation:
Nernst equation relates the reduction potential of a reaction (half-cell or full cell reaction) to the standard electrode potential, temperature, and activities of the chemical species that is undergoing reduction and oxidation.
E = E° - Q
E - Cell potential
E° - Standard cell potential
R - Gas constant
T - Temperature
n - Number of electrons transferred in the reaction (from balanced reaction)
F - Faraday constant (96,500 C/mol)
Q - Reaction quotient
At standard temperature T = 298 K, = 0.0592 V
Then the Nernst equation can ne rewritten as :
E = E° - Q
At equilibrium, E = 0 and Q =
where is the equilibrium constant.
Equation can be rearranged to obtain the following relation:
=