what is peroxide effect ?
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The change in regioselectivity of the addition of HBr to an alkene or alkyne in the presence of a peroxide. ... In the absence of a peroxide, HBr adds to propene via an ionic mechanism (with a carbocation intermediate) to give 2-bromopropane. Markovnikov's Rule is obeyed.
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The change in regioselectivity of the addition of HBR to an alkene...........
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