What is role of co in the purification of Ni??
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Solution :
a) Role of cryolite
It lowers the melting points of the mixture .
It makes alumina a good conduction of electricity
(b) When nickel is heated with carbon monoxide it forms a volatile complex nickel tetracarbonyl which on further heating at higher temperature decomposes to give pure nickle.
Ni+4CO330−350k−→−−−−−−−Ni(CO)4450−470k−→−−−−−−−Ni+4CONi+4CO330−350k→Ni(CO)4450−470k→Ni+4CO
a) Role of cryolite
It lowers the melting points of the mixture .
It makes alumina a good conduction of electricity
(b) When nickel is heated with carbon monoxide it forms a volatile complex nickel tetracarbonyl which on further heating at higher temperature decomposes to give pure nickle.
Ni+4CO330−350k−→−−−−−−−Ni(CO)4450−470k−→−−−−−−−Ni+4CONi+4CO330−350k→Ni(CO)4450−470k→Ni+4CO
devanshuooohooda:
i wrote two because you confused me if co is carbon monoxide or coryoliye
Answered by
2
Hey friend....
Heres your answer
Solution :
a) Role of cryolite
It lowers the melting points of the mixture .
It makes alumina a good conduction of electricity
(b) When nickel is heated with carbon monoxide it forms a volatile complex nickel tetracarbonyl which on further heating at higher temperature decomposes to give pure nickle.
Ni+4CO330−350k−→−−−−−−−Ni(CO)4450−470k−→−−−−−−−Ni+4CO
HOPE IT HELPS YOU!
THANKS
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