What is sigma bond ? Explain s-s overlapping and p-p overlapping .
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Explanation:
Sigma bonds are further classified as s-s , s-p & p-p bonds. s-s bonds are formed by overlapping of two s orbitals. p-p sigma bond is formed by overlapping of two p orbitals and. s-p sigma bonds are formed by overlappig of one s and one p orbita.
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- If the overlaping is done along the nuclear axis ( head on overlaping ) , it forms sigma bond.
- When two s-s orbitals overlap along the nuclear axis .
- For ex -
- When two p-p orbitals overlap ( Pz - Pz overlapping ) .
- For ex -
Note :-
- Pz orbital is present at nuclear axis therefore it always forms bond , while Px and Py forms π bond.
( See attachments )
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